July/August 2007, Volume 3, Issue 7
Published by AEGIS Communications
Direct Composite Resins
Luis Guilherme Sensi, DDS, MS, PhD; Howard E. Strassler, DMD; and William Webley
Esthetic and restorative dentistry aims to replace lost or damaged structures with artificial materials that possess biological, physical, and functional properties similar to natural teeth.1 Among these materials, composite resins occupy a paramount position because they offer excellent esthetic potential and acceptable longevity without the need for extensive sound structure preparation, allowing minimally invasive preparation or sometimes no preparation at all.2 Numerous composite systems have been developed in recent years with a multitude of shades, translucencies, opacities, and effects that, together with innovative placement techniques, make the fabrication of restorations that faithfully emulate the polychromatic variations and optical characteristics present in natural teeth possible.3-5 This conceptual evolution in materials and techniques gives clinicians the option to treat a large range of problems faced in everyday practice in a reliable, predictable, and conservative way. Because direct composite restorations are now a more integral part of restorative procedures, to provide improved patient care dentists should have an in-depth knowledge regarding the properties, indications of use, and clinical performance of these materials.
Composite Resin Formulations
Composite resins are basically a mixture of an organic resin matrix, inorganic filler particles, and a coupling agent. The resin matrix consists of monomers, initiator systems, stabilizers, and pigments, while the inorganic filler consists of some form of glass filler particles. Although there are variations of the specific composition and distribution of the matrix and filler phases in every commercial composite resin, most composites are fabricated using either bisphenol-A-diglycidylmethacrylate (bis-GMA) or urethane dimethacrylate (UDMA) matrix polymers and different kinds of filler particles, such as glass, quartz, and colloidal silica.6 The matrix and the filler are the components that dictate most of the material’s mechanical properties (ie, fracture toughness and elastic modulus), as well as physical properties (ie, polishability and optical characteristics). Also, the relationship between the resin matrix and the filler’s particle size and loading defines the different types of composite resins available today.
Classification of Composite Resins
Composite resins have been classified according to various characteristics (ie, curing mechanism and particle type); however, the most commonly used classification considers mainly the distribution and average particle size of a given composite’s filler phase.7 Even though macrofilled composite resins are still available on the market (ie, Adaptic®, Johnson & Johnson, New Brunswick, NJ; Concise, 3M ESPE, St. Paul, MN), their use is very restricted because their limited properties lead to less than optimal clinical performance (ie, roughness, staining, wear, and discoloration). Most composite resins can be classified in two main categories: microfilled and hybrid composites.
Microfilled Composite Resins
These composites were introduced in the early 1980s. They are generally filled 35% to 50% by weight with prepolymerized 0.02-µm to 0.04-µm silicon dioxide filler particles. The main characteristics of these composites are the high polish that can be achieved and maintained over time and excellent enamel-like translucency. Therefore, they are indicated for the restoration of anterior teeth and cervical abfraction lesions; they should not be used in heavy stress-bearing areas because they frequently exhibit marginal chipping and bulk fracture.7
In general, their physical properties are inferior to those of hybrid composites because of their lower percentage of filler content; the exception is their compressive strength, which can be relatively high. Microfilled composites have higher coefficients of thermal expansion, greater water sorption, greater polymerization shrinkage, lower module of elasticity, lower tensile strength, and lower fracture toughness.6
Examples of microfilled composites currently available include: Durafill® VS (Heraeus Kulzer Inc, Armonk, NY), Renamel® Microfill (Cosmedent, Inc, Chicago, IL), Matrixx Restoratives Anterior Microfill (Discus Dental, Culver City, CA), and EPIC®-TMPT (Parkell, Inc, Edgewood, NY).
Clinical evaluations comparing anterior restorations produced with microfills and hybrid composite resins have demonstrated that hybrid composites present a significantly better performance with regard to marginal integrity, color, and marginal discoloration.8,9 Some reinforced microfill composite resins are also available and are indicated for use in posterior teeth, such as Heliomolar®/Heliomolar® HB (Ivoclar Vivadent, Amherst, NY) and Virtuoso Sculptable® (Den-Mat, Santa Maria, CA). Good clinical results have been reported with these composites.10
With the trend toward simplification, together with the search for “universal” materials and the evolution of hybrid materials, the use of microfilled composites will become more restricted.
Hybrid Composite Resins
Hybrid composite resins contain a heterogeneous aggregate of filler particles. They are usually filled 70% to 80% by weight with 0.04-µm and 1-µm to 5-µm filler particles. The average particle size of hybrid composites is usually > 1 µm. This mixture of fillers accounts for their excellent physical properties with high polishability when compared to the earlier macrofilled composites. Regrettably, one problem with hybrid composite resins is their inability to maintain their gloss.11 Some examples of hybrid composite resins include: Herculite XRV (Sybron Dental Specialties Inc/Kerr Dental, Orange, CA), Spectrum® TPH® (DENTSPLY Caulk, Milford, DE), and Charisma® (Heraeus Kulzer Inc).
Given the need for a highly polishable composite resin with optimal physical properties for use in the anterior and posterior regions, manufacturers developed microhybrid composite resins. They reduced the particle size, ranging from 0.04 µm to 1 µm (Figure 1). By incorporating smaller particles, microhybrid composites polish and handle better than their hybrid counterparts. Microhybrid composites are stronger than most microfilled composites and can be used in both anterior and posterior teeth. Therefore, microhybrid composites can be used as universal or all-purpose composite resins.7 Some of the available microhybrid composite resins are: Filtek Z250 (3M ESPE), Synergy® D6 (Coltène/Whaledent® Inc, Cuyahoga Falls, OH), Gradia Direct (GC America, Alsip, IL), Point 4 (Kerr Dental), Renamel® Universal Microhybrid (Cosmedent), Tetric® Ceram (Ivoclar Vivadent, Inc), and Venus® (Heraeus Kulzer Inc).
Although these materials can be used with basic shades, many of these new composites also have a complete set of incisal, enamel, dentin, and effect shades so they can be built using a stratification technique for a more toothlike appearance (Figure 2; Figure 3; Figure 4). A number of manufacturers include specialized shade guides and recipes to help the clinician choose the best mix of shades to use in specific circumstances. Some good examples of these elaborate kits are: 4 Seasons® (Ivoclar Vivadent, Inc), Vit-l-escence® (Ultradent Products, Inc, South Jordan, UT), Miris® (Coltène/Whaledent® Inc), and Artiste Nano-Hybrid Flowable Composite (Pentron Clinical Technologies, Wallingford, CT).
Regarding consistency, the great majority of microhybrid composite resins present medium viscosity; however, some other types of composite resins can be classified as high-viscosity (“packable” composites) or low-viscosity (“flowable” composites) (Figure 5). High-viscosity composite resins (also known as “condensable” or “heavy-body”), possess a greater amount of load (above of 80% in volume), which makes them more resistant and easier to apply because of their excellent sculptability. The use of these composite resins is especially indicated for the reestablishment of the contour and proximal contacts in class 2 restorations and for the precise definition of occlusal anatomy features.11 As the clinical performance of these composites is similar to that of regular-viscosity microhybrid composites, the selection of this type of material must be based on individual preferences.12 Some available brands include P60 (3M ESPE), Virtuoso Packable® (Den-Mat), Alert® Condensable Composite (Pentron Clinical Technologies), and Tetric® Ceram HB (Ivoclar Vivadent, Inc).
On the other hand, flowable composite resins present much less load (about 50% in volume), possess inferior mechanical properties, and present a greater degree of polymerization shrinkage.13 Recent studies have demonstrated that the use of flowable composites does not improve the marginal sealing of adhesive restorations;14,15 however, its use is indicated in areas of difficult access and irregular cavity preparations because it favors the insertion and adaptation of the subsequent increments.16 These composite resins are also useful in the restoration of highly conservative preparations such as placing preventive resin re-storations, repairing margins of existing composite resin restorations, surfacing fiber splints, repairing bis-Acryl composite provisional restoration margins, luting porcelain veneers, and placing temporary pedodontic restorations.11,17 Some of the available materials include: Flow-it® ALC (Pentron Clinical Technologies), Aelite Flo® (Bisco, Inc, Schaumburg, IL), Clearfil Majesty Flow (Kuraray America Inc, New York, NY), and PermaFlo® (Ultradent Products, Inc). Some manufacturers have developed flowable composites that are part of a family of composites with their esthetic microhybrid composites. Examples include Gradia® Flowable (GC America), Filtek Supreme Plus Flowable (3M ESPE), Point 4 Flowable (Kerr Dental); and Virtuoso Flowable® (Den-Mat).
Nanofilled Composite Resins
Nanofilled composites were recently introduced and they consist of nanomers (5 nm to 75 nm particles) and “nanocluster” agglomerates as the fillers. Nanoclusters are agglomerates (0.6 µm to 1.4 µm) of primary zirconia/silica nanoparticles (5 nm to 20 nm in size) fused together at points of contact, and the resulting porous structure is infiltrated with silane.18 The nanofilled composites present similar mechan-ical and physical properties to those of microhybrid composites, but when it comes to polish and gloss retention they perform significantly better.19 The main example of nanofilled composites is Filtek Supreme Plus. However, several manufacturers are now incorporating nano-sized particles into their formulations, resulting in the creation of yet another category, the “nanohybrid” composites. Some examples are: Premise (Kerr Dental), Aelite Aesthetic Enamel (Bisco, Inc), Clearfil Majesty Esthetic (Kuraray America, Inc), and Artiste. Some clinical examples can be seen in Figure 6 ; Figure 7 ; Figure 8 ; Figure 9 ; Figure 10 ; Figure 11 ; Figure 12.
The evolution in the development and improvements with composite resins has changed the way dentists practice restorative dentistry. Currently, the new generations of composite resins offer excellent performance materials for anterior and posterior direct placement restorations. When selecting composite resins, the criteria should include highly esthetic shade matching, translucency, and fluorescence; high polishability; excellent mechanical properties that contribute to restoration durability; good handling properties; excellent wear resistance; radiopacity; low polymerization shrinkage; and biocompatibility. The criteria for future development and introduction of new composite resins point to the progression to one universal composite.20 This is a difficult challenge to manufacturer and clinician alike. To date, in general, the microhybrid and nanofilled composites offer an alternative to microfilled composites in their ability to be highly polishable with toothlike translucency. This class of composites would be considered universal-use composite resins. Clinicians can expect excellent mechanical properties, excellent esthetics with shade selection, good color stability, stain resistance, low wear, and good polishability when using these composites.11
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About the Authors
Luis Guilherme Sensi, DDS, MS, PhD
Department of Endodontics, Prosthodontics and Operative Dentistry
University of Maryland Dental School
Howard E. Strassler, DMD
Professor and Director of Operative Dentistry
Department of Endodontics, Prosthodontics and Operative Dentistry
University of Maryland Dental School
Undergraduate Dental Student
University of Maryland Dental School